The Tetherless World Constellation (TWC) at Rensselaer Polytechnic Institute (RPI) proposes to facilitate the vocabulary and ontology development within the context of the overall development of semantic prototypes for the National Climate Assessment (NCA) portals using a combination of environmental inter-agency collaborations in a use-case focused workshop setting, information modeling, and software developments and deployments. The prototypes are intended to provide search and browse options that inspire confidence that all relevant information has been found; data providers will be citable with detailed provenance generation. Expected deliverables are: information models, vocabulary and ontology services for vetted climate assessment settings, and search/ browse prototypes.